Role of aggregated Fe oxo species in N2O decomposition over Fe/ZSM-5
نویسندگان
چکیده
منابع مشابه
Dynamics of N2O decomposition over HZSM-5 with low Fe content
The dynamics of N2O decomposition to gaseous nitrogen and oxygen over HZSM-5 catalysts with a low iron content (200 and 1000 ppm) was studied by the transient response method in the temperature range 523–653 K. The active catalysts were prepared from HZSM-5 with Fe in the framework on its steaming at 823 K followed by thermal activation in He at 1323 K. Two main steps were distinguished in the ...
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The fractal dimensions of FeZSM-5 zeolites were used to characterize the change in their geometry depending on different postsynthesis treatments. The fractal dimension values were estimated from the Dubinin–Astakhov isotherms of nitrogen adsorption and related to the activity of these zeolites in the benzene hydroxylation to phenol by nitrous oxide. The zeolites had two different iron contents...
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Ru is considered as an effective active species for N2O decomposition; however, there is disagreement about which ruthenium species is key for catalytic activity. In order to understand the role of Ru species in N2O decomposition, Ru/Al2O3 (Ru/Al2O3-H2, Ru/Al2O3-NaBH4, Ru/Al2O3-air) catalysts with different ratios of metallic Ru were prepared and evaluated for their catalytic activities. Variou...
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The catalytic decomposition of N2O was investigated over Cu-Zn/ZnAl2O4 catalysts in the temperature range of 400–650 ◦C Catalytic samples have been prepared by wet impregnation method. Prepared catalysts were characterized using several techniques like BET surface area, X-ray diffraction (XRD), and Scanning electron microscopy (SEM). The Cu-Zn/ZnAl2O4 showed higher catalytic performance along w...
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ژورنال
عنوان ژورنال: Chinese Journal of Catalysis
سال: 2014
ISSN: 1872-2067
DOI: 10.1016/s1872-2067(14)60184-4